pCO2 distributions and air-water CO2 fluxes in the Columbia River estuary

Sources of time and space variability in the distributions of surface water carbon dioxide partial pressure (pCO₂) and air-water CO₂ flux were quantified in the Columbia River estuary (CRE) during five cruises in spring, summer and autumn 2007/08. The CRE is an upwelling margin river-dominated mesotidal system that is an estuary class not represented in global flux compilations. Data from the CRE show instances of pCO2 under and oversaturation with respect to the atmosphere during every season in association with tidal, wind, biological and storm driven sources of variability. On average the CRE is a sink for atmospheric CO₂ during spring and a source during summer and autumn, with large positive air-water CO₂ fluxes during the snowmelt freshet coinciding with the functional transition in the estuary. It is hypothesized here that interannual variability in size of the snowmelt freshet largely influences the extent of springtime CO₂ uptake in the CRE, and subsequently the magnitude of net annual CO₂ emission from the estuary. Data collected during an autumn storm show that large fluxes can drop quickly, even in the presence of high gas transfer velocities, because of rapid CO₂ exchange with the atmosphere in this weakly buffered system. Combining seasonal observations of CO₂ exchange with an assumption of winter conditions, we estimate that the net annual emission from the CRE is approximately 1 mol C m^-2 yr^-1. The air-water CO₂ fluxes reported here are the first from an upwelling margin river-dominated mesotidal estuary, and the estimate of net annual exchange is substantially lower than those from other tidal and/or large river systems represented in global flux compilations.